There is a sticky link at the top of this forum with a link to downloading the "TestComplete Made Easy" document that takes you through a LOT of the app and the different capabilities.
As for information, because each AUT is different, we cannot necessarily tell you what to do with yours. My suggestion is to read the documentation (that manual I just mentioned is FANTASTIC) and start using the app.
AutomatedQA also does provide training seminars. You might want to investigate attending one of those.